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Effect of Catalyst Layer Hydrophobicity on Fe−N−C Proton Exchange Membrane Fuel Cells
Author(s) -
Zhang Xinyue,
Liu Qingtao,
Shui Jianglan
Publication year - 2020
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.202000351
Subject(s) - proton exchange membrane fuel cell , catalysis , materials science , membrane electrode assembly , cathode , durability , power density , chemical engineering , layer (electronics) , polytetrafluoroethylene , emulsion , composite number , current density , membrane , composite material , contact angle , diffusion , electrochemistry , electrode , chemistry , electrolyte , organic chemistry , power (physics) , physics , biochemistry , quantum mechanics , engineering , thermodynamics
The hydrophobicity of the cathode catalyst layer (CCL) affects the performance of the proton exchange membrane fuel cell (PEMFC) by adjusting the water management of the catalyst layer, which has been extensively studied in Pt‐based catalysts. Here, the effect of the hydrophobicity of Fe−N−C CCL on the performance of the PEMFC is investigated. The hydrophobicity of the Fe−N−C CCL is tuned by polytetrafluoroethylene (PTFE) by using three addition methods: 1) coat PTFE on Fe−N−C powder and heat‐treat; 2) mix PTFE emulsion with Fe−N−C ink and then brush the electrode; and 3) transfer a ground PTFE/Fe−N−C composite film onto the gas diffusion layer by the decal method. For each PTFE addition method, the optimized PTFE amount can increase the power density of Fe−C−N PEMFC by 15.1 %, 26.6 %, and 87.2 %, respectively. At the same time, it is found that enhanced hydrophobicity reduces the initial current decay rate of the Fe−N−C CCLs, but their residual current densities are close after a 50 h durability test at 0.5 V in a H 2 ‐O 2 PEMFC. It can be concluded that the hydrophobicity of the Fe−N−C CLL has a great influence on the power density of the fuel cell, but the influence on the long‐term durability of the fuel cell is negligible.