Cu−Ni Bimetallic Hydroxide Catalyst for Efficient Electrochemical Conversion of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid | Zendy

Chen Hao | Zendy; Wang Jiatuan | Zendy; Yao Yuan | Zendy; Zhang Zihao | Zendy; Yang Zhenzhen | Zendy; Li Jing | Zendy; Chen Kequan | Zendy; Lu Xiuyang | Zendy; Ouyang Pingkai | Zendy; Fu Jie | Zendy

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Cu−Ni Bimetallic Hydroxide Catalyst for Efficient Electrochemical Conversion of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid

Author(s) -

Chen Hao,

Wang Jiatuan,

Yao Yuan,

Zhang Zihao,

Yang Zhenzhen,

Li Jing,

Chen Kequan,

Lu Xiuyang,

Ouyang Pingkai,

Fu Jie

Publication year - 2019

Publication title -

chemelectrochem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.182

H-Index - 59

ISSN - 2196-0216

DOI - 10.1002/celc.201901366

Subject(s) - bimetallic strip , catalysis , terephthalic acid , yield (engineering) , 5 hydroxymethylfurfural , coke , hydroxide , chemistry , electrochemistry , materials science , nuclear chemistry , inorganic chemistry , organic chemistry , metallurgy , electrode , polyester

2,5‐furandicarboxylic acid (2,5‐FDCA) produced from 5‐hydroxymethylfurfural (5‐HMF) is a promising renewable alternative to terephthalic acid. In this work, we prepared a Cu−Ni bimetallic catalyst with a CuNi(OH) 2 structure by incipient wetness impregnation. This catalyst gave a 9.2 mA cm −2 current density for 5‐HMF oxidation at 1.45 V vs RHE. Finally, 100 % conversion of HMF with 93.3 % yield of 2,5‐FDCA was obtained.

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