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Synthesis of the Urchin‐Like NiS@NiCo 2 S 4 Composites on Nickel Foam for High‐Performance Supercapacitors
Author(s) -
Yang Ping,
Feng Lina,
Hu Jun,
Ling Wenqin,
Wang Shaohua,
Shi Jianjun,
Yang Zhangfu,
Wang Fengwu
Publication year - 2020
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201901304
Subject(s) - supercapacitor , materials science , pseudocapacitor , capacitance , current density , nickel , electrode , composite material , carbon nanotube , power density , hydrothermal circulation , chemical engineering , metallurgy , chemistry , power (physics) , physics , quantum mechanics , engineering
A simple hydrothermal treatment process was used to prepare urchin‐like NiS@NiCo 2 S 4 composites on Ni foam, which were then employed as binder‐free and conductive‐agent‐free electrodes for pseudocapacitors. The as‐synthesized composites have significant capacitive performance because of the novel porous structure. A specific capacitance up to 14.32 F cm −2 was obtained at a current density of 5 mA cm −2 , which was far higher than that of pristine NiCo 2 S 4 nanotube arrays (about 8.4 F cm −2 ). More importantly, Ni@NiS@NiCo 2 S 4 and activated carbon (AC) were assembled as the positive and negative electrode, respectively, in an asymmetric supercapacitor, which possesses prominent performance. In addition to 78.7 % capacitance retention when cycling at 50 mA cm −2 for 5000 cycles, the as‐fabricated Ni@NiS@NiCo 2 S 4 //AC device exhibits a high energy density of 38.96 Wh kg −1 and power density of 339.62 W kg −1 at a current density of 10 mA cm −2 .