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Mosaic Red Phosphorus/MoS 2 Hybrid as an Anode to Boost Potassium‐Ion Storage
Author(s) -
Gao Yuqing,
Ru Qiang,
Liu Yang,
Cheng Shikun,
Wei Li,
Ling Francis ChiChung,
Chen Fuming,
Hou Xianhua
Publication year - 2019
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201901166
Subject(s) - anode , materials science , gravimetric analysis , potassium , ion , phosphorus , charge cycle , chemical engineering , battery (electricity) , metallurgy , chemistry , electrode , power (physics) , physics , organic chemistry , quantum mechanics , trickle charging , engineering
Low‐cost, non‐toxic, and abundant red phosphorus (RP) with high gravimetric discharge/charge capacity has been recognized as a promising anode candidate for potassium‐ion batteries (KIBs). However, the large volumetric change, severe agglomeration, and rapid capacity attenuation during discharge/charge cycles are major obstacles for practical applications in potassium‐ion storage. In order to eliminate such intrinsic deficiencies, a mosaic RP/MoS 2 hybrid is designed and prepared by using a simple ball‐milling method and subsequently used as an anode for KIBs. The hybrid with a certain ratio of 2 : 1 can achieve a sustainable K + storage capability (246.6/239.6 mAh g −1 for 100 cycles at 50 mA g −1 ), considerable long‐cycle performance (120.5/118.0 mAh g −1 at 1000 mA g −1 after 500 cycles), and good rate capability. The cycling performance is attributed to a pseudocapacitive effect, controllable interlayer spacing of MoS 2 , and enhanced conductivity. In view of the scalable synthesis process and considerable cycling durability, the RP/MoS 2 hybrid may shed light on the rational design of novel anode alternatives for KIBs.