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Fluorination of Li‐Rich Lithium‐Ion‐Battery Cathode Materials by Fluorine Gas: Chemistry, Characterization, and Electrochemical Performance in Half Cells
Author(s) -
Breddemann Ulf,
Erickson Evan M.,
Davis Victoria,
Schipper Florian,
Ellwanger Mathias,
Daub Michael,
Hoffmann Anke,
Erk Christoph,
Markovsky Boris,
Aurbach Doron,
Krossing Ingo
Publication year - 2019
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201900733
Subject(s) - chemistry , fluorine , x ray photoelectron spectroscopy , dielectric spectroscopy , analytical chemistry (journal) , lithium (medication) , electrochemistry , thermal stability , secondary ion mass spectrometry , amorphous solid , scanning electron microscope , magic angle spinning , chemical engineering , electrode , ion , materials science , nuclear magnetic resonance spectroscopy , crystallography , organic chemistry , composite material , medicine , engineering , endocrinology
Mild fluorination of high‐energy nickel‐cobalt‐manganese (HE‐NCM) materials with low pressures of elementary fluorine gas (F 2 ) at room temperature was systematically studied. The fluorinated HE‐NCM samples were analysed by ion chromatography, inductively coupled plasma mass spectrometry, FT‐IR spectroscopy, powder X‐ray diffraction, magic angle spinning NMR spectroscopy, scanning electron microscopy, thermo‐gravimetric analysis, differential thermal analysis, electrochemical testing, and X‐ray photoelectron spectroscopy. The treatment of the cathode materials with low pressures (a few hundred mbar) of elementary fluorine gas at room temperature led to the elimination of the basic surface film (LiOH, Li 2 CO 3 , Li 2 O, etc.), and the resulting thin amorphous LiF film led to increased capacity and long‐term stability of the battery. Impedance built‐up was greatly reduced for these systems throughout cycling. Fluorination with F 2 only causes the formation of O−Me−F bonds (Me=Transition Metal), when treated with F 2 at higher pressures. If O−Me−F bonds are formed, it may be detrimental to the electrode surface film resistance and cycle stability of the electrodes. However, it may be that the LiF surface content, which can expand as long as the LiMeO 2 structure can be oxidized and Li + can be extracted, has become too large and thus detrimental. Considering the evolution of differential capacity plots and taking into account the thermodynamic driving force of the F 2 treatment, it is likely that the same activation processes that occur electrochemically in Li‐rich materials also occur chemically, when the material is exposed to F 2 . Differential capacity plots show enhanced Mn 4+ reduction peaks upon lithiation, when the material was exposed to F 2 , only possible after activation of the Li 2 MnO 3 phase. For this reason, we believe fluorination promotes to some extent an activation of this phase.