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Physicochemical and Electrochemical Properties of 1,1,2,2‐Tetrafluoroethyl‐2,2,3,3‐Tetrafluoropropyl Ether as a Co‐Solvent for High‐Voltage Lithium‐Ion Electrolytes
Author(s) -
Xia Lan,
Lee Saixi,
Jiang Yabei,
Li Shiqi,
Liu Zhaoping,
Yu Linpo,
Hu Di,
Wang Shuhan,
Liu Yitong,
Chen George Z.
Publication year - 2019
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201900729
Subject(s) - electrolyte , electrochemistry , separator (oil production) , faraday efficiency , lithium (medication) , chemical engineering , materials science , solvent , ethylene carbonate , high voltage , ion , ether , electrode , trimethyl phosphate , inorganic chemistry , chemistry , voltage , organic chemistry , phosphate , medicine , physics , quantum mechanics , engineering , thermodynamics , endocrinology
Although high‐voltage positive electrode materials for high energy density lithium‐ion batteries have gained a great attention, the lack of compatible electrolytes with sufficiently high oxidative stability to deliver an excellent cycling ability restricts their practical application. Fluorinated solvents are considered as promising candidates for high‐voltage electrolyte solvents. In this study, we select 1,1,2,2‐tetrafluoroethyl‐2,2,3,3‐tetrafluoropropyl ether (TTE) with a high boiling point, low cost, and good SEI‐filming ability as a co‐solvent of fluoroethylene carbonate‐based electrolytes and extensively investigate its physicochemical and electrochemical properties for applications in high‐voltage lithium‐ion batteries. Our experimental results show that the TTE‐containing electrolyte exhibits not only a high oxidative stability up to 5.5 V ( vs . Li/Li + ), but also excellent wettability with the separator. In addition to high discharge capacity and increased coulombic efficiency of the Li/LiNi 0.5 Mn 1.5 O 4 half‐cell assembled with the TTE‐containing electrolyte cycled between 3.0 and 4.9 V, the cell also displays a high rate capability. This work shows that partially fluorinated ethers, e. g., TTE, are promising co‐solvents for high‐voltage electrolytes that can enable commercial development of high energy density lithium‐ion batteries.