Electrochemical Synthesis of 3‐Bromoimidazo[1,2‐a]pyridines Directly from 2‐Aminopyridines and  alpha ‐Bromoketones | Zendy

Jian WenQian | Zendy; Wang HaiBin | Zendy; Du KeSi | Zendy; Zhong WeiQiang | Zendy; Huang JingMei | Zendy

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Electrochemical Synthesis of 3‐Bromoimidazo[1,2‐a]pyridines Directly from 2‐Aminopyridines and alpha ‐Bromoketones

Author(s) -

Jian WenQian,

Wang HaiBin,

Du KeSi,

Zhong WeiQiang,

Huang JingMei

Publication year - 2019

Publication title -

chemelectrochem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.182

H-Index - 59

ISSN - 2196-0216

DOI - 10.1002/celc.201900406

Subject(s) - aminopyridines , electrolysis , halogenation , electrochemistry , substrate (aquarium) , chemistry , combinatorial chemistry , condensation , domino , medicinal chemistry , organic chemistry , physics , electrode , catalysis , thermodynamics , oceanography , electrolyte , geology

A highly efficient co‐electrolysis of 3‐bromoimidazo[1,2‐a]pyridines has been developed in a simple undivided cell without any external oxidant. This protocol proceeds smoothly to provide the products with a broad substrate scope through a domino condensation/bromination sequence. Importantly, it can be easily scaled up.

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