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Fluorinated Nanographite as a Cathode Material for Lithium Primary Batteries
Author(s) -
Wang Li,
Li Yanyan,
Wang Shuo,
Zhou Pengfei,
Zhao Zengdian,
Li Xiaowei,
Zhou Jin,
Zhuo Shuping
Publication year - 2019
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201900194
Subject(s) - materials science , lithium (medication) , fluorine , cathode , electrochemistry , stacking , energy density , chemical engineering , phase (matter) , porosity , carbon fibers , nanotechnology , power density , composite material , chemistry , organic chemistry , power (physics) , electrode , metallurgy , engineering physics , physics , medicine , endocrinology , quantum mechanics , composite number , engineering
Abstract Lithium/fluorinated carbon (Li/CF x ) batteries face the problems of low rate performance and initial voltage delay. Herein, we propose a novel type of fluorinated nanographite as a cathode material for Li/CF x batteries through the direct fluorination of nanographite. The structure of fluorinated nanographite, including crystalline phase, particle size, fluorine content, and the properties of C−F bonding, strongly depend on the fluorination temperature. The fluorinated nanographite prepared at 450 °C (FG‐450) shows the highest specific capacity, 837.4 mAh g −1 at 10 mA g −1 , along with a discharge plateau of 2.54 V, responding to an energy density of 2004.5 Wh kg −1 . The highlights of the fluorinated nanographite are to deliver high rate performance and overcome the initial voltage delay. FG‐450 can be discharged at a high rate of about 3.6 C, delivering a high power density of 5460 W kg −1 with a remaining energy density of 1030.5 Wh kg −1 . The good electrochemical performance of the FG‐450 sample is ascribed to the combined effect of its nanoparticle size, large specific surface area, and continuous stacking porosity.