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Synthesis of Graphite Oxide/Cobalt Molybdenum Oxide Hybrid Nanosheets for Enhanced Electrochemical Performance in Supercapacitors and the Oxygen Evolution Reaction
Author(s) -
Ahmed Jahangeer,
Ubaidullah Mohd,
Ahmad Tokeer,
Alhokbany Norah,
Alshehri Saad M.
Publication year - 2019
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201900055
Subject(s) - cyclic voltammetry , materials science , supercapacitor , electrochemistry , scanning electron microscope , cobalt oxide , oxide , linear sweep voltammetry , chemical engineering , electrode , chemistry , metallurgy , composite material , engineering
Reduced graphite oxide (rGO)/cobalt molybdenum oxide (CoMoO 4 ) hybrid nanosheets (NSs) have been prepared by using the hydrothermal method followed by detailed characterization with X‐ray diffraction, electron microscopy, Raman and FTIR spectroscopy. The unusual rGO/CoMoO 4 hybrid NSs allow the electrochemical reactions of electrodes for supercapacitors. Therefore, an excellent specific capacitance (ca. 450 F/g at 2 mV/s) and stability performance of the rGO/CoMoO 4 hybrid NSs were observed in alkaline medium (i. e. 5 M KOH electrolyte). The rGO/CoMoO 4 hybrid NSs show five times higher specific capacitance compared to pure CoMoO 4 NSs. The cyclic stability of the rGO/CoMoO 4 hybrid NSs reveals retention of approximately 98 % of the initial capacitance after 1500 cycles. Moreover, the rGO/CoMoO 4 hybrid electrocatalyst shows higher oxygen evolution activity than CoMoO 4 NSs in 0.1 M KOH versus Ag/AgCl. Cyclic voltammetry (CV), galvanostatic charge‐discharge (GCD), linear sweep voltammetry (LSV), and chronoamperometric (CA) measurements strongly support the enhanced electrochemical performance of the rGO/CoMoO 4 hybrid NSs.