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Hierarchical, Vertically‐Oriented Carbon Nanowall Foam Supercapacitor using Room Temperature Ionic Liquid Mixture for AC Line Filtering with Ultrahigh Energy Density
Author(s) -
Bo Zheng,
Xu Chenxuan,
Yang Huachao,
Shi Hao,
Yan Jianhua,
Cen Kefa,
Ostrikov Kostya
Publication year - 2019
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201801825
Subject(s) - supercapacitor , ionic liquid , electrolyte , materials science , capacitance , energy storage , electrolytic capacitor , diffusion , capacitor , energy density , quasi solid , ion , chemical engineering , nanotechnology , optoelectronics , voltage , electrode , electrical engineering , dye sensitized solar cell , power (physics) , chemistry , engineering physics , organic chemistry , physics , quantum mechanics , thermodynamics , engineering , catalysis
Supercapacitors have been considered as a promising alternative of aluminum electrolytic capacitors (AECs) for AC line filtering applications. However, realizing supercapacitors with fast frequency response and superior energy density still remains an open issue. Herein, we demonstrate a hierarchical, vertically‐oriented carbon nanowall foam (CWF) supercapacitor using mixed room temperature ionic liquids (RTILs) for high‐performance AC line filtering. Hierarchical CWF exhibits macrospores as electrolyte reservoirs to shorten ion transport distance, vertically‐oriented, open channels to enable fast ion diffusion and consecutive scaffolds to promote electron transfer. CWF supercapacitor using RTIL mixture realizes a recorded‐high areal energy density of 1.23 μWh cm −2 at 120 Hz (almost ∼2.0 times/∼10.0 times larger than those of organic/aqueous electrolytes, respectively) and fast frequency response (RC time constant=∼1.3 ms). More importantly, CWF supercapacitor achieves a capacitance advantage over commercial AECs up to 1,000 V, substantially larger than those reported in state‐of‐the‐art literatures (maximum of ∼250 V).

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