Anodic Formation of Aryl Mesylates through Dehydrogenative Coupling Reaction | Zendy

Möhle Sabine | Zendy; Herold Sebastian | Zendy; Hillerson Natalie D. | Zendy; Waldvogel Siegfried R. | Zendy

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Anodic Formation of Aryl Mesylates through Dehydrogenative Coupling Reaction

Author(s) -

Möhle Sabine,

Herold Sebastian,

Hillerson Natalie D.,

Waldvogel Siegfried R.

Publication year - 2019

Publication title -

chemelectrochem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.182

H-Index - 59

ISSN - 2196-0216

DOI - 10.1002/celc.201800498

Subject(s) - electrolysis , cyclic voltammetry , anode , aryl , naphthalene , coupling reaction , electrochemistry , chemistry , coupling (piping) , carbon fibers , materials science , inorganic chemistry , photochemistry , combinatorial chemistry , organic chemistry , electrode , catalysis , metallurgy , composite material , alkyl , composite number , electrolyte

The first direct anodic mesylation of aromatic substrates was established. The installation of the oxygen‐carbon bond was achieved through a dehydrogenative coupling reaction, which works with naphthalene in preparative attractive yields, and this protocol can be applied to a range of other aromatic substrates. The electroconversion is conducted at carbon anodes in a divided cell. The constant current conditions allow electrolysis with a simple electronic periphery. The results are in full accordance with cyclic voltammetry studies, providing a consistent picture.

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