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High‐Performance Asymmetric Li‐Ion Pseudocapacitors Based on Pyroprotein Nanowebs
Author(s) -
Cho Se Youn,
Kim Na Rae,
Jin HyoungJoon,
Yun Young Soo
Publication year - 2017
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201700301
Subject(s) - pseudocapacitor , materials science , nanofiber , energy storage , electrospinning , heteroatom , chemical engineering , electrochemistry , supercapacitor , amorphous solid , microstructure , nanotechnology , specific energy , electrode , polymer , chemistry , composite material , power (physics) , organic chemistry , ring (chemistry) , physics , quantum mechanics , engineering
Modern industrial technologies require high power and energy storage devices with long‐term cycling stabilities; the electrochemical performances of these devices are mainly dependent on the active electrode materials and their energy storage mechanisms. In this study, nanoweb‐structured pyroprotein nanofibers (NW‐PNFs) were prepared from electrospun silk protein by pyrolysis. NW‐PNFs have an open macroporous structure formed by entangled nanofibers and numerous micropores originating from the amorphous pseudographitic microstructure of the nanofibers. In addition, they possessed a large number of heteroatoms (10.3 at. % oxygen and 5.2 at. % nitrogen). These material properties led to superior Li‐ion storage performances with high reversible capacity of about 1,050 mA h g −1 at 0.5 A g −1 and great cycling performance over 3,000 cycles. In particular, NW‐PNFs exhibited high rate capability even at the specific current of 50 A g −1 , at which the high specific capacity of circa 400 mA h g −1 was achieved. Furthermore, asymmetric Li‐ion storage devices based on NW‐PNFs showed feasible electrochemical performances with a maximum specific energy of 235.7 Wh kg −1 at 188.6 W kg −1 and maximum power of 21,220 W kg −1 at 69.6 Wh kg −1 .