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Interlayer‐Expanded Vanadium Oxychloride as an Electrode Material for Magnesium‐Based Batteries
Author(s) -
Minella Christian Bonatto,
Gao Ping,
ZhaoKarger Zhirong,
Mu Xiaoke,
Diemant Thomas,
Pfeifer Maxim,
Chakravadhanula Venkata S. K.,
Behm R. Juergen,
Fichtner Maximilian
Publication year - 2017
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201700034
Subject(s) - vanadium , x ray photoelectron spectroscopy , anode , cyclic voltammetry , electrode , intercalation (chemistry) , materials science , electrochemistry , analytical chemistry (journal) , dielectric spectroscopy , inductively coupled plasma , scanning electron microscope , chemical engineering , chemistry , inorganic chemistry , plasma , composite material , metallurgy , chromatography , physics , quantum mechanics , engineering
Mg‐based batteries, which use the Mg 2+ shuttle, theoretically offer several advantages compared to the Li technology, such as higher theoretical volumetric capacity (3833 mA h cm −3 ) of the Mg‐metal anode, the possibility to be safely handled in air, and dendrite‐free electrodeposition. In this study, vanadium oxychloride was employed as an electrode material in a Mg‐based battery. As the cell delivered just 45 mA h g −1 in the first cycle, we tried to improve the delivered capacity through preliminary cycling of the VOCl electrode with Li. The strategy is based on the ability of VOCl to expand its interlayer spacing upon intercalation of ions or molecules within them. In fact, a VOCl electrode with expanded interlayer spacing should facilitate the intercalation of Mg 2+ , thus leading to higher specific capacities. The Li pretreatment was able to promote the specific capacity by a factor of four (170 mA h g −1 ) after the first discharge at 298 K. Over 130 mA h g −1 was retained at 5 mA g −1 after 70 cycles. Structural and electrochemical characterization was carried out by means of galvanostatic charge/discharge tests, cyclic voltammetry, ex situ X‐ray photoelectron spectroscopy, X‐ray diffraction, transmission electron microscopy coupled with energy‐dispersive X‐ray spectroscopy, and electron energy loss spectroscopy. Inductively coupled plasma optical emission spectrometry was used to determine the concentration of lithium in the electrode.