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Application of Wet Nanostructured Bacterial Cellulose as a Novel Hydrogel Bioanode for Microbial Fuel Cells
Author(s) -
Mashkour Mehrdad,
Rahimnejad Mostafa,
Mashkour Mahdi,
Bakeri Gholamreza,
Luque Rafael,
Oh SangEun
Publication year - 2017
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201600868
Subject(s) - microbial fuel cell , bacterial cellulose , dielectric spectroscopy , chemical engineering , cyclic voltammetry , materials science , nanocomposite , polypyrrole , graphite , cellulose , fourier transform infrared spectroscopy , electrochemistry , conductivity , nuclear chemistry , chemistry , nanotechnology , electrode , composite material , anode , engineering
In this study, wet bacterial cellulose (BC) with a water content of more than 98% was utilized as a novel scaffold to design bioanodes for microbial fuel cells (MFCs). At first, unmodified wet BC was used a bioanode. Then a simple in situ synthesis of polypyrrole (PPYR) at various pyrrole concentrations was subsequently performed on the BC‘s fibers to generate the novel bioanodes. Characterization of the BC‐PPYR nanobiocomposites was conducted by using ATR‐FTIR, XRD, and FESEM. The performance of the nanobiocomposites was studied in a MFC system by using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and polarization curves. A power density of 136 mW/m 2 and a current density of 662 mA/m 2 were found for BC‐PPYR, which are superior to those of graphite (1 mW/m 2 and 9 mA/m 2 , respectively). The results were attributed to a good adhesion of bacterial cells to the fibrous surface of BC, permanent capillary transfer of nutrients, the conductive content of hydrogel BC, and good conductivity and catalytic activity of PPYR in the nanocomposite.