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Ionic‐Liquid Tag with Multiple Functions in Electrochemical Glycosylation
Author(s) -
Nokami Toshiki,
Sasaki Norihiko,
Isoda Yuta,
Itoh Toshiyuki
Publication year - 2016
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201600311
Subject(s) - ionic liquid , glycosylation , electrochemistry , chemistry , intramolecular force , combinatorial chemistry , extraction (chemistry) , electrolyte , ether , chromatography , organic chemistry , catalysis , biochemistry , electrode
A benzyl‐ether‐type ionic‐liquid tag (IL tag) was developed and applied for electrochemical glycosylation. The IL tag was shown to display multifunctional roles in the glycosylation: the tag in thioglycosides worked as both an intramolecular electrolyte for the anodic oxidation and a stereo‐controlling group; it also enabled easy extraction of the products after the reaction.