Ionic‐Liquid Tag with Multiple Functions in Electrochemical Glycosylation | Zendy

Nokami Toshiki | Zendy; Sasaki Norihiko | Zendy; Isoda Yuta | Zendy; Itoh Toshiyuki | Zendy

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Ionic‐Liquid Tag with Multiple Functions in Electrochemical Glycosylation

Author(s) -

Nokami Toshiki,

Sasaki Norihiko,

Isoda Yuta,

Itoh Toshiyuki

Publication year - 2016

Publication title -

chemelectrochem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.182

H-Index - 59

ISSN - 2196-0216

DOI - 10.1002/celc.201600311

Subject(s) - ionic liquid , glycosylation , electrochemistry , chemistry , intramolecular force , combinatorial chemistry , extraction (chemistry) , electrolyte , ether , chromatography , organic chemistry , catalysis , biochemistry , electrode

A benzyl‐ether‐type ionic‐liquid tag (IL tag) was developed and applied for electrochemical glycosylation. The IL tag was shown to display multifunctional roles in the glycosylation: the tag in thioglycosides worked as both an intramolecular electrolyte for the anodic oxidation and a stereo‐controlling group; it also enabled easy extraction of the products after the reaction.

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