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NiFe Layered‐Double‐Hydroxide‐Derived NiO‐NiFe 2 O 4 /Reduced Graphene Oxide Architectures for Enhanced Electrocatalysis of Alkaline Water Splitting
Author(s) -
Zhang Guoquan,
Li Yanfang,
Zhou Yufei,
Yang Fenglin
Publication year - 2016
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201600301
Subject(s) - overpotential , electrocatalyst , materials science , non blocking i/o , tafel equation , water splitting , graphene , catalysis , hydroxide , oxygen evolution , oxide , chemical engineering , nickel oxide , inorganic chemistry , electrochemistry , nanotechnology , chemistry , metallurgy , photocatalysis , electrode , biochemistry , engineering
Electrochemical water splitting is an environmentally friendly technology to store renewable but intermittent energy into hydrogen fuels. Nowadays, exploiting low‐costing, high‐performance, and robust catalysts for the electrochemical oxygen evolution reaction (OER) is essential to improve the overall efficiency of water splitting. Herein, the synthesis, structural characterization, and electrocatalytic OER performance of NiO‐NiFe 2 O 4 nanoparticles anchored on reduced graphite oxide frameworks (NiO‐NiFe 2 O 4 /rGO) were investigated. Facile thermal annealing of the NiFe layered double hydroxide (NiFe‐LDH) precursor led to the formation of highly dispersible NiO‐NiFe 2 O 4 nanoparticles (20–30 nm in size) across the rGO substrate with a NiO/NiFe 2 O 4 molar ratio up to 4.42. In contrast to the nanostructured NiFe‐LDH/rGO catalyst, the NiO‐NiFe 2 O 4 /rGO nanohybrid exhibits a lower OER onset potential ( E onset =1.436 V vs. RHE), affords a smaller overpotential of 296 mV, and achieves a current density of 10 mA cm −2 with a Tafel slope of about 43 mV dec −1 ; these values are comparable to those of the benchmark IrO 2 catalyst. The synergy between the abundant catalytically active sites through good dispersion of NiO‐NiFe 2 O 4 across the rGO substrate and fluent electron transport arising from the rGO and NiFe 2 O 4 components results in the outstanding electrocatalytic activity. The extremely high catalytic activity, facile synthesis, and low‐cost of the NiO‐NiFe 2 O 4 /rGO nanohybrid make it a very promising catalyst for the OER.