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Contrasts between Mild and Harsh Oxidation of Carbon Nanotubes in terms of their Properties and Electrochemical Performance
Author(s) -
Gusmão Rui,
Sofer Zdeněk,
Nováček Michal,
Pumera Martin
Publication year - 2016
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201600082
Subject(s) - carbon nanotube , electrochemistry , materials science , impurity , electron transfer , metal , nanotechnology , chemical engineering , characterization (materials science) , carbon fibers , molecule , electrode , chemistry , organic chemistry , composite material , metallurgy , composite number , engineering
Fundamental studies and electrochemical applications of carbon nanotubes (CNTs) have impacted a wide range of disciplines. A key issue for CNT electrochemistry is to understand how the physical, chemical, and electronic properties of different CNT materials affect their electrochemical performance. We investigate the differences arising from CNTs undergoing mild (H 2 O 2 ) or harsh (HNO 3 ) oxidation processes. Morphological assessment and chemical characterization of CNT materials revealed that HNO 3 treatment (CNT–HNO 3 ) was effective in removing a large part of the metallic impurities, whereas H 2 O 2 treatment (CNT–H 2 O 2 ) was more proficient in eliminating carbonaceous imperfections in the starting CNT material (CNT prist ). We investigated the electrocatalytic and electron‐transfer properties of CNT prist and oxidized CNTs on a variety of electrochemical probes, which are sensitive to carbon surfaces as well as its oxygen‐containing groups and/or metallic impurities. Electrochemical results show that, for the studied molecules, CNT prist and CNT–H 2 O 2 exhibit mostly indistinguishable performances, whereas CNT–HNO 3 yields an improved performance.