Premium
Intrinsic Iron‐Containing Multiwalled Carbon Nanotubes as Electro‐Fenton Catalyst for the Conversion of Benzene to Redox‐Active Surface‐Confined Quinones
Author(s) -
Vishnu Nandimalla,
Kumar Annamalai Senthil
Publication year - 2016
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201600052
Subject(s) - hydroquinone , cyclic voltammetry , catalysis , redox , fourier transform infrared spectroscopy , inorganic chemistry , carbon nanotube , raman spectroscopy , nuclear chemistry , benzene , chemistry , electrochemistry , materials science , photochemistry , chemical engineering , electrode , organic chemistry , nanotechnology , engineering , physics , optics
Multiwalled carbon nanotubes containing an iron impurity (2.1 wt %) (MWCNT‐Fe*) were used to modify a glassy carbon electrode (GCE/MWCNT‐Fe*), which was subsequently exploited for the electrochemical oxidation of benzene (BZ) to redox‐active and surface‐confined quinones (BZO) in H 2 O 2 containing pH 2 HCl–KCl. Physicochemical and electrochemical characterization methods, such as transmission electron microscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, UV/Vis spectroscopy, liquid chromatography coupled mass spectroscopy, and cyclic voltammetry studies with naked Fe 3+/2+ , catechol (CA), and hydroquinone (HQ), evidenced that, in the presence of H 2 O 2 , the intrinsic iron impurity in MWCNT‐Fe* follows the electro‐Fenton reaction to oxidize BZ to BZO (CA+HQ) on the surface of MWCNT‐Fe* (i.e. GCE/MWCNT‐Fe*@BZO). Electro‐catalytic oxidation of hydrazine was demonstrated as a model system for the application of the GCE/MWCNT‐Fe*@BZO catalyst.