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Hybrid C 3 N 4 /Fluorine‐Doped Tin Oxide Electrode Transfers Hydride for 1,4‐NADH Cofactor Regeneration
Author(s) -
Cazelles R.,
Liu J.,
Antonietti M.
Publication year - 2015
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201402421
Subject(s) - cofactor , tin oxide , nicotinamide adenine dinucleotide , electrode , tin , inorganic chemistry , chemistry , electrochemistry , oxide , fluorine , nicotinamide , nitride , photoelectrochemistry , materials science , nad+ kinase , enzyme , organic chemistry , layer (electronics)
Herein, we report the use of graphitic carbon nitride (C 3 N 4 )‐modified fluorine‐doped tin oxide electrodes for the electroregeneration of reduced nicotinamide adenine dinucleotide phosphate (NADH). We synthesized and functionalized these hybrid electrodes by using anodic aluminum‐oxide‐templated C 3 N 4 growth. Electrochemical activation of the semiconducting C 3 N 4 islands with a rhodium complex permits selective regeneration of biologically active 1,4‐NADH cofactor.