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A Comparative Study on the Electrodeposition of Tin from Two Different Ionic Liquids: Influence of the Anion on the Morphology of the Tin Deposits
Author(s) -
Giridhar Pulletikurthi,
Elbasiony Amr M.,
Zein El Abedin Sherif,
Endres Frank
Publication year - 2014
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.201402155
Subject(s) - tin , ionic liquid , cyclic voltammetry , scanning electron microscope , electrochemistry , morphology (biology) , ionic bonding , inorganic chemistry , dicyanamide , materials science , ion , chemistry , electrode , metallurgy , organic chemistry , catalysis , composite material , biology , genetics
The electrodeposition of tin from two ionic liquids (ILs) containing the 1‐butyl‐1‐methylpyrrolidinium cation ([Py 1,4 ] + ) and the trifluoromethylsulfonate (TfO − ) or dicyanamide (DCA − ) anion is investigated by cyclic voltammetry, scanning electron microscopy (SEM), infrared (IR) spectroscopy and X‐ray diffraction. Cyclic voltammetry is employed to evaluate the electrochemical behaviour of SnCl 2 in the two ILs, and IR spectroscopy is used to study the difference in the complexation of SnCl 2 in the two ILs. The electrodeposition of tin is also studied in [EMIm]DCA ([EMIm] + =1‐ethyl‐3‐methylimidazolium), for the purpose of comparison. The morphology of the electrodeposited tin from the different ILs is investigated by SEM, which shows that the morphology of the tin deposits changes upon changing the IL. Agglomerated tin deposits are obtained on gold and copper from [Py 1,4 ]TfO. Tin dendrites were obtained both from [Py 1,4 ]DCA and [EMIm]DCA. This study reveals that a change in the ionic composition (anion) of the IL can influence the morphology of electrodeposits of tin and presumably of other elements and compounds.