Kinetics and mechanisms of reaction between carbon disulphide and morpholine in aqueous solutions | Zendy

Alper Erdogan | Zendy; Bouhamra Walid | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Kinetics and mechanisms of reaction between carbon disulphide and morpholine in aqueous solutions

Author(s) -

Alper Erdogan,

Bouhamra Walid

Publication year - 1994

Publication title -

chemical engineering and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.403

H-Index - 81

eISSN - 1521-4125

pISSN - 0930-7516

DOI - 10.1002/ceat.270170212

Subject(s) - morpholine , aqueous solution , kinetics , chemistry , carbon fibers , chemical kinetics , chemical engineering , organic chemistry , materials science , engineering , physics , quantum mechanics , composite material , composite number

The reaction in aqueous solutions between carbon disulphide and morpholine has been studied experimentally at 303 K using a conductimetric stopped‐flow technique. The observed pseudo‐first order rate constant does not vary linearly with amine concentration but follows the equation:\documentclass{article}\pagestyle{empty}\begin{document}$$ k_{obs} = k_{Am} [R_2 NH]^2 + k_w [R_2 NH][H_2 O] $$\end{document}. This equation is compatible both with (i) zwitterion intermediate and (ii) single‐step termolecular reaction mechanisms which were previously proposed for the corresponding reactions of CO 2 and COS. Values of rate constants k Am and k w at 303 K are also reported.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research