Evaluation of standard thermodynamic parameters for the sorption of  n ‐hexane and methanol in zeolites | Zendy

Pal Tapan Kumar | Zendy; Majumder Asitava | Zendy; Raha Tarun Kumar | Zendy; Fetting Fritz | Zendy

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Evaluation of standard thermodynamic parameters for the sorption of n ‐hexane and methanol in zeolites

Author(s) -

Pal Tapan Kumar,

Majumder Asitava,

Raha Tarun Kumar,

Fetting Fritz

Publication year - 1990

Publication title -

chemical engineering and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.403

H-Index - 81

eISSN - 1521-4125

pISSN - 0930-7516

DOI - 10.1002/ceat.270130140

Subject(s) - mordenite , sorption , hexane , adsorption , methanol , chemistry , zeolite , thermodynamics , atmospheric temperature range , chromatography , organic chemistry , catalysis , physics

Adsorption isotherms for n ‐hexane and methanol in mordenite and ZSM5 in the temperature range from 323 K to 473 K were found to be of type 1. The adsorbate‐adsorbent interaction (C 1 ) and adsorbate‐adsorbate interaction (C 2 ) wee computed according to Bradley and Wilkins model, whereas the Rees and Williams model predicts the adsorption characteristics. Finally, the thermodynamic parameters such as Δ G o , Δ S o , Δ H o , K , K + have been evaluated for the sorption of n ‐hexane in mordenite and ZSM5.

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