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Polyacrylonitrile/ α ‐Fe 2 O 3 Hybrid Photocatalytic Composite Adsorbents for Enhanced Dye Removal
Author(s) -
Mohammadreza Miraboutalebi Seyed,
Peydayesh Mohammad,
Bagheri Maryam,
Mohammadi Toraj
Publication year - 2020
Publication title -
chemical engineering and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.403
H-Index - 81
eISSN - 1521-4125
pISSN - 0930-7516
DOI - 10.1002/ceat.202000140
Subject(s) - polyacrylonitrile , freundlich equation , adsorption , composite number , langmuir , photocatalysis , aqueous solution , materials science , methylene blue , chemical engineering , chemistry , nuclear chemistry , composite material , organic chemistry , catalysis , polymer , engineering
The potential of a novel α ‐Fe 2 O 3 /polyacrylonitrile (PAN) hybrid composite adsorbent to eliminate methylene blue (MB) from aqueous solution was evaluated. PAN was selected as the base composite. The presence of α ‐Fe 2 O 3 as nanophotocatalyst on the surface of PAN introduced an efficient photocatalytic hybrid composite adsorbent for degrading MB. Effects of α ‐Fe 2 O 3 nanopowder loading, pH, temperature, MB initial concentration, solar light, and contact time were investigated. Langmuir, Freundlich, and Temkin isotherms were applied to analyze the adsorption behavior. The Freundlich equation provided the best correlation with experimental data. Pseudo‐first‐order, pseudo‐second‐order, and intraparticle models were employed. Thermodynamic studies indicated an endotherm and spontaneous adsorption process in a defined temperature range.