Vapor Liquid Equilibria for Ionic Liquid/Ethanol/Water Systems and the Effect of Anion Hydrolysis | Zendy

Faghihi Erfaneh | Zendy; Mokhtarani Babak | Zendy; Mortaheb Hamid Reza | Zendy; Heydar Kourosh Tabar | Zendy; Mirzaei Mojtaba | Zendy; Sharifi Ali | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Vapor Liquid Equilibria for Ionic Liquid/Ethanol/Water Systems and the Effect of Anion Hydrolysis

Author(s) -

Faghihi Erfaneh,

Mokhtarani Babak,

Mortaheb Hamid Reza,

Heydar Kourosh Tabar,

Mirzaei Mojtaba,

Sharifi Ali

Publication year - 2020

Publication title -

chemical engineering and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.403

H-Index - 81

eISSN - 1521-4125

pISSN - 0930-7516

DOI - 10.1002/ceat.202000114

Subject(s) - tetrafluoroborate , ionic liquid , chemistry , hydrolysis , ethanol , inorganic chemistry , dehydration , isobaric process , organic chemistry , thermodynamics , catalysis , biochemistry , physics

The performance of two tetrafluoroborate‐based ionic liquids (ILs) as entrainers in the dehydration of water/ethanol azeotropic mixtures was evaluated. Isobaric vapor‐liquid equilibrium (VLE) data were measured for the systems ethanol/water/1‐butyl‐3‐methyl imidazolium tetrafluoroborate and ethanol/water / n ‐butylpyridinium tetrafluoroborate including the azeotropic region. VLE data for the ethanol/water, ethanol/IL, and water/IL binary mixtures were obtained at 100 kPa. The hydrolysis of the tetrafluoroborate anion was studied for both types of ILs by 19 F NMR analysis. The hydrolysis of the tetrafluoroborate anion does not have much effect on the ethanol/water VLE. The 19 F NMR analysis indicated that hydrolysis occurred at high mole fractions of water.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research