Premium
Detection of Copper Bisguanidine NO Adducts by UV‐vis Spectroscopy and a SuperFocus Mixer
Author(s) -
Oppermann Alexander,
Laurini Larissa,
Etscheidt Fabian,
Hollmann Katharina,
Strassl Florian,
Hoffmann Alexander,
Schurr Daniela,
Dittmeyer Roland,
Rinke Günter,
Herres-Pawlis Sonja
Publication year - 2017
Publication title -
chemical engineering and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.403
H-Index - 81
eISSN - 1521-4125
pISSN - 0930-7516
DOI - 10.1002/ceat.201600691
Subject(s) - electron paramagnetic resonance , chemistry , delocalized electron , adduct , copper , spectroscopy , saturation (graph theory) , analytical chemistry (journal) , density functional theory , absorption spectroscopy , photochemistry , radical , absorption (acoustics) , electron paramagnetic resonance spectroscopy , inorganic chemistry , nuclear magnetic resonance , materials science , organic chemistry , computational chemistry , physics , mathematics , quantum mechanics , combinatorics , composite material
The reaction of Cu(I) bisguanidine complexes with nitric oxide and the formation of intermediate species were monitored via UV‐vis spectroscopy at low temperature, with the occurrence of characteristic absorption bands. The origin of the emerging species and their character were substantiated by electron paramagnetic resonance (EPR) measurements and density functional theory (DFT) studies showing a delocalized {CuNO} 11 radical species. Furthermore, this system was transferred to the SuperFocus mixer setup, which allows rapid mixing and the determination of decay constants at ambient temperatures of the thermally sensitive species. However, these experiments demonstrated the limits of these systems, such as the NO saturation in organic solvents and a preferably precise temperature control within the SuperFocus mixer, which should be addressed in the future.