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Industrial Process Design for the Production of Aniline by Direct Amination
Author(s) -
Driessen Rick T.,
Kamphuis Peter,
Mathijssen Lydwien,
Zhang Ruo,
van der Ham Louis G. J.,
van den Berg Henk,
Zeeuw Arend Jan
Publication year - 2017
Publication title -
chemical engineering and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.403
H-Index - 81
eISSN - 1521-4125
pISSN - 0930-7516
DOI - 10.1002/ceat.201600635
Subject(s) - amination , aniline , hydroxylamine , raw material , production (economics) , benzene , chemistry , process engineering , organic chemistry , waste management , engineering , catalysis , economics , macroeconomics
The objective is to design a plant from raw material to product for the production of aniline by direct amination of benzene. The process design is started on a conceptual level and ended on a basic engineering level as well as a techno‐economical evaluation. The amination of benzene by hydroxylamine was used as basis. For the production of hydroxylamine four routes are proposed. The most promising route is the chemical reduction of nitric oxide with hydrogen. The process evaluation shows that 27 % of the atomic nitrogen is lost. The atomic carbon efficiency is close to unity. Furthermore, a significant amount of steam can be produced. From an economical perspective, there is still room for improvement because the return of investment is quite low and the payback period is quite high.