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Cumene Hydroperoxide Hydrogenation on a Pd/Al 2 O 3 Catalyst in a Trickle Bed Reactor – Kinetics of Hydrogenation and Deactivation
Author(s) -
Ma Y.,
Zhu Q.C.
Publication year - 2012
Publication title -
chemical engineering and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.403
H-Index - 81
eISSN - 1521-4125
pISSN - 0930-7516
DOI - 10.1002/ceat.201100657
Subject(s) - catalysis , chemistry , cumene , kinetics , cumene hydroperoxide , hydrogen , trickle bed reactor , chemical kinetics , photochemistry , inorganic chemistry , organic chemistry , physics , quantum mechanics
Liquid‐phase hydrogenation using a Pd/Al 2 O 3 catalyst provides a potential technique for the reduction of cumene hydroperoxide (CHP) to α‐cumyl alcohol (CA). In this paper, CHP hydrogenation was carried out in a cocurrent downflow trickle‐bed reactor over a wide range of reaction conditions to study the reaction and deactivation kinetics. The proposed intrinsic rate expression for CHP hydrogenation is based on an Eley‐Rideal mechanism that accounts for an irreversible surface reaction between the absorbed CHP with nonabsorbed hydrogen molecules. During CHP hydrogenation, an exponential decay in activity of the Pd/Al 2 O 3 catalyst and the presence of residual activity were observed. A kinetic deactivation model with residual activity was developed. Based on reaction and deactivation kinetics, catalyst deactivation was attributed to oxidation of the catalyst surface by CHP. The presence of residual activity was due to the partial reduction of oxidized catalyst surface by hydrogen.