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Reactivation and Reuse of a Hydrotreating Spent Catalyst for Cyclohexene Conversion
Author(s) -
Ahmed H. S.,
Menoufy M. F.
Publication year - 2009
Publication title -
chemical engineering and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.403
H-Index - 81
eISSN - 1521-4125
pISSN - 0930-7516
DOI - 10.1002/ceat.200800542
Subject(s) - hydrodesulfurization , cyclohexene , catalysis , leaching (pedology) , chemistry , hydrocarbon , hydrogen , cyclohexane , inorganic chemistry , oxalic acid , atmospheric pressure , nuclear chemistry , organic chemistry , environmental science , oceanography , soil science , soil water , geology
A comparative study has been made on the efficiency of leaching, using different concentrations of oxidized oxalic acid, and thermally treating techniques to reactivate a Ni‐Mo‐spent hydrotreating catalyst. The reactivation of the treated catalysts was performed in a pulse microcatalytic reactor under atmospheric pressure of hydrogen and reaction temperatures ranging from 250 °C to 450 °C using cyclohexene as model hydrocarbon. The studies revealed that a decoking spent catalyst after leaching using a low concentration (2 %) enhanced its physical characteristics (surface area and average pore diameter) and catalytic activity towards maximum cyclohexene hydrogenation and hydroisomerization reactions at 300 °C and 350 °C, respectively.

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