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Application of Interference Microscopy and IR Microscopy for Characterizing and Investigating Mass Transport in Nanoporous Materials
Author(s) -
Heinke L.,
Chmelik C.,
Kortunov P.,
Ruthven D. M.,
Shah D. B.,
Vasenkov S.,
Kärger J.
Publication year - 2007
Publication title -
chemical engineering and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.403
H-Index - 81
eISSN - 1521-4125
pISSN - 0930-7516
DOI - 10.1002/ceat.200700093
Subject(s) - nanoporous , interference microscopy , microscopy , zeolite , chemical engineering , adsorption , desorption , infrared microscopy , materials science , kinetics , mass transfer , molecular sieve , methanol , analytical chemistry (journal) , interference (communication) , infrared , chemistry , nanotechnology , catalysis , chromatography , optics , organic chemistry , physics , engineering , quantum mechanics , channel (broadcasting) , electrical engineering
The application of interference microscopy has provided an important breakthrough in the study of the transport of guest molecules in nanoporous materials, making it possible to observe the transient intracrystalline concentration profiles resulting from a well‐defined change (usually a step) in the ambient gas pressure. This approach was used to study adsorption and desorption kinetics in several zeolite systems. The advantages of this technique, especially when combined with infrared absorption measurements, are illustrated by experimental results obtained in a study of the methanol‐ferrierite system.