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Surface Properties and Catalytic Performance of La 0.8 K 0.2 Cu x Mn 1–x O 3 for Simultaneous Removal of NO x and Soot
Author(s) -
Peng X. S.,
Lin H.,
Shangguan W. F.,
Huang Z.
Publication year - 2007
Publication title -
chemical engineering and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.403
H-Index - 81
eISSN - 1521-4125
pISSN - 0930-7516
DOI - 10.1002/ceat.200600224
Subject(s) - catalysis , x ray photoelectron spectroscopy , nox , porosity , soot , copper , bet theory , chemistry , chemical engineering , specific surface area , oxygen , inorganic chemistry , materials science , metallurgy , combustion , organic chemistry , engineering
The influence of copper substitution in La 0.8 K 0.2 Cu x Mn 1–x O 3 on its catalytic performance for simultaneous removal of NO x and soot under oxygen rich conditions was investigated. A series of catalysts was prepared and then characterized by XRD, SEM, BET, and XPS. The temperature programmed reaction (TPR) method was used to evaluate the catalytic performance of the catalysts. XRD results show that the partial substitution of Cu for Mn promotes the formation of perfect perovskites. SEM and BET results demonstrate that appropriate copper substitution enhances the porosity and increases the specific surface area, leading to conditions which are favorable for heterogeneous catalysis. XPS results indicate that a fraction of the Mn 3+ is converted to Mn 4+ on the addition of low levels of Cu. By correlation of the physicochemical properties and the catalytic performance, a large specific surface area, high porosity, high content of Mn 3+ and synergistic effects of Mn 3+ and Cu 2+ are seen to favor the simultaneous catalytic removal of NO x and soot.