Pincer‐Type Phosphorus Compounds With Boryl‐Pendant And Application In Catalytic H 2  Generation From Ammonia‐Borane: A Theoretical Study | Zendy

Yang Deshuai | Zendy; Bao Panqing | Zendy; Yang Zhen | Zendy; Chen Zhaoxu | Zendy; Sakaki Shigeyoshi | Zendy; Maeda Satoshi | Zendy; Zeng Guixiang | Zendy

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Pincer‐Type Phosphorus Compounds With Boryl‐Pendant And Application In Catalytic H 2 Generation From Ammonia‐Borane: A Theoretical Study

Author(s) -

Yang Deshuai,

Bao Panqing,

Yang Zhen,

Chen Zhaoxu,

Sakaki Shigeyoshi,

Maeda Satoshi,

Zeng Guixiang

Publication year - 2021

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.202100661

Subject(s) - pincer movement , ammonia borane , borane , catalysis , chemistry , phosphorus , ammonia , medicinal chemistry , organic chemistry , dehydrogenation

Metal‐free catalysts composed of heavy main group element(s) have been limited. Herein, a theoretical study unveils that pincer‐type phosphorus compound bearing a boryl‐pendant is good catalyst for H 2 generation from ammonia borane through phosphorus‐boryl (P−B) cooperation function. Pincer‐type phosphorus compound without boryl‐pendant is not active for this reaction, indicating the important role of the P−B cooperation function.

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