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NiFe‐layered Double Hydroxide/Vertical Bi 2 WO 6 Nanoplate Arrays with Oriented {001} Facets Supported on ITO Glass: Improved Photoelectrocatalytic Activity and Mechanism Insight
Author(s) -
Wang Yajun,
Liu Liming,
Zhang Jiaying,
Zhang Wencan,
Yao Wenqing,
Jiang Guiyuan
Publication year - 2021
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.202100166
Subject(s) - photocatalysis , materials science , photocurrent , hydroxide , electrochemistry , substrate (aquarium) , chemical engineering , dielectric spectroscopy , degradation (telecommunications) , catalysis , nanotechnology , electrode , optoelectronics , chemistry , telecommunications , biochemistry , oceanography , computer science , engineering , geology
The hole oxidation of Bi 2 WO 6 occurs on Bi or O sites, thus, enhancing the proportion of {001} facets of Bi 2 WO 6 in photocatalysis has received increased attention because of its promotion of the hole oxidation. In this work, we successfully fabricated {001} facets highly exposed Bi 2 WO 6 nanoplate arrays (Bi 2 WO 6 NAs) photoelectrode growing on indium tin oxides (ITO) substrate in situ. After electrochemical deposition of NiFe‐layered double hydroxide (LDH) on Bi 2 WO 6 NAs, NiFe−LDH/Bi 2 WO 6 NAs photoelectrode was also obtained for the first time. Bi 2 WO 6 with a large proportion of {001} facets facilitate the photocatalytic oxidation reactions, and NiFe−LDH can induce photogenerated holes transfer from Bi 2 WO 6 to NiFe−LDH simultaneously. The NiFe−LDH/Bi 2 WO 6 NAs photoelectrode presents superior photoelectrochemical properties than pure Bi 2 WO 6 NAs photoelectrode, which was characterized by transient photocurrent and electrochemical impedance spectroscopy (EIS) systematically. Taking bisphenol A (BPA) as a model pollutant, the NiFe−LDH/Bi 2 WO 6 NAs photoelectrode exhibits much higher photocatalytic (PC) and photoelectrocatalytic (PEC) degradation activity than Bi 2 WO 6 NAs photoelectrode. The PEC degradation rate of NiFe−LDH/Bi 2 WO 6 NAs photoelectrode is 2.1 times and 4.7 times that of Bi 2 WO 6 NAs photoelectrode under simulated solar light illumination and visible light illumination, respectively. This work proposes a new approach to construct highly efficient photoelectrode for contaminant purification.