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Cover Feature: Crystallographic Visualization of a Double Water Molecule Addition on a Pt 1 ‐MOF during the Low‐temperature Water‐Gas Shift Reaction (ChemCatChem 4/2021)
Author(s) -
Bilanin Cristina,
Tiburcio Estefanía,
FerrandoSoria Jesús,
Armentano Donatella,
LeyvaPérez Antonio,
Pardo Emilio
Publication year - 2021
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.202001985
Subject(s) - water gas shift reaction , reactivity (psychology) , chemistry , molecule , metal organic framework , catalysis , single crystal , water gas , cover (algebra) , crystal structure , crystallography , inorganic chemistry , organic chemistry , medicine , alternative medicine , pathology , adsorption , engineering , syngas , mechanical engineering
The Cover Feature shows the presence of Pt 1 single atoms, within the channels of a metal‐organic framework (MOF), which are capable of catalyzing, at low temperature, the water‐gas‐shift reaction (WGSR). In their Full Paper, C. Bilanin et al. show evidence that a double water attack occurs in the Pt‐catalyzed low‐temperature WGSR by a combination of reactivity experiments with soluble Pt catalysts, kinetic and spectroscopic measurements, and operando single crystal X‐ray diffraction on the Pt 1 ‐MOF, which constitute a clear step forward on the understanding of the mechanism of the WGSR. More information can be found in the Full Paper by C. Bilanin et al.