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Aerobic Alcohol Oxidation by a Zeolitic Octahedral Metal Oxide based on Iron Vanadomolybdates Under Mild Conditions
Author(s) -
Zhu Qianqian,
Yin Shanshan,
Zhou Mengyuan,
Wang Jie,
Chen Chaomin,
Hu Panpan,
Jiang Xizhuo,
Zhang Zhenxin,
Li Yanshuo,
Ueda Wataru
Publication year - 2021
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.202001696
Subject(s) - redox , alcohol oxidation , microporous material , chemistry , octahedron , catalysis , aldehyde , alcohol , selectivity , oxide , inorganic chemistry , metal , cinnamyl alcohol , organic chemistry , crystal structure
Zeolitic octahedral metal oxides are fully‐inorganic crystalline materials with the multi‐component redox property and the intrinsic microporosity. The redox active zeolitic iron vanadomolybdate acts as a catalyst for aerobic oxidation of primary aromatic alcohols. Molecular oxygen is able to be activated in the material due to the confinement effect of the micropore and the unique redox property of the framework. Different primary aromatic alcohols are oxidized by the material, and high alcohol conversion and aldehyde selectivity are achieved. The material is stable and able to be reused for 5 times without loss of activity.