Premium
n ‐Butyllithium Catalyzed Hydroboration of Nitriles and Carbodiimides
Author(s) -
Yan Ben,
He Xing,
Ni Congjian,
Yang Zhi,
Ma Xiaoli
Publication year - 2021
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.202001669
Subject(s) - hydroboration , chemistry , catalysis , organic chemistry , solvent , functional group , butyllithium , polymer
Highly efficient and selective hydroboration of nitriles and carbodiimides with pinacolborane (HBpin) is achieved by using the simple and convenient n ‐BuLi as a catalyst. Solvent‐free and good functional group tolerance under mild conditions have been achieved. A possible mechanistic pathway of the n ‐BuLi catalyzed hydroboration of nitriles with HBpin is proposed.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom