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Molecularly Controlled Catalysis – Targeting Synergies Between Local and Non‐local Environments
Author(s) -
Chatterjee Basujit,
Chang WeiChieh,
Werlé Christophe
Publication year - 2021
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.202001431
Subject(s) - context (archaeology) , pillar , catalysis , nanotechnology , function (biology) , biochemical engineering , sustainability , process management , chemistry , business , engineering , materials science , mechanical engineering , ecology , paleontology , evolutionary biology , biology , biochemistry
Future chemicals should preserve the efficiency of their function while reducing hazards and waste. In this context, catalysis – a fundamental pillar of Green Chemistry – is still the most effective technique capable of meeting societal requirements while offering sustainability. To further push the boundaries of catalysis and respond to these challenges, a clear understanding of the molecular level interactions is essential. To succeed, we believe it is necessary to consider the transition metal catalyst as a molecular system encompassing a local and non‐local environment. The synergistic effects that are taking place between the ligand, the metal center, and their surrounding environments primarily determine the efficiency of the bond making and breaking processes. This Concept provides tools for identifying, implementing, and combining these effects to control catalysis directly at a molecular level.