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Decoupling Oxygen and Chlorine Evolution Reactions in Seawater using Iridium‐based Electrocatalysts
Author(s) -
Ko Jesse S.,
Johnson James K.,
Johnson Phillip I.,
Xia Zhiyong
Publication year - 2020
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.202000653
Subject(s) - overpotential , tafel equation , oxygen evolution , iridium , chemistry , catalysis , electrocatalyst , seawater , inorganic chemistry , electrochemistry , electrode , organic chemistry , oceanography , geology
A series of iridium (Ir) organometallic‐based electrocatalysts fused onto high surface‐area activated carbon using pyrolysis were prepared for the oxygen evolution reaction (OER) in seawater electrolysis. These catalysts had a low loading of Ir (<6 wt%), while also inducing atom coordination to the Ir center. The morphology and chemical composition of these electrocatalysts were analyzed by scanning electron microscopy, energy dispersive spectroscopy, and X‐ray photoelectron spectroscopy, which all showed a uniform dispersion of Ir and heteroatom‐doped moieties. To assess electrocatalytic activity, we used an artificial electrolyte comprising 0.1 M HClO 4 +3.5 wt% NaCl, and found that these catalysts delivered a low overpotential of 243 mV, a low Tafel slope (92 mV dec −1 ), and a high exchange current density (1.4 mA cm −2 ). By using a headspace chlorine gas (Cl 2 ) detector in situ , we discovered that a Cl 2 content of 27 ppm was present. When tested in synthetic seawater, the overpotential exhibited a two‐fold increase, yet Cl 2 was undetected, thus indicating favorable OER kinetics. This significant finding exemplifies the need for in situ Cl 2 detection for seawater splitting research, since further insight can be derived to help guide the design of novel electrocatalysts.