Premium
SBA‐15 Supported Chiral Phosphine‐Gold(I) Complex: Highly Efficient and Recyclable Catalyst for Asymmetric Cycloaddition Reactions
Author(s) -
Yan Dong,
Wang Nannan,
Xue Teng,
Wu Haihong,
Zhang Junliang,
Wu Peng
Publication year - 2020
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.202000514
Subject(s) - cycloaddition , phosphine , catalysis , chemistry , mesoporous material , enantioselective synthesis , combinatorial chemistry , covalent bond , sulfur , organic chemistry
Abstract Ordered mesoporous SBA‐15 supported chiral phosphine gold (I) complexes were successfully developed. The gold(I) complexes were covalently immobilized on mercaptopropyl modified SiO 2 surface through radical reaction. In this way, the chiral carbon and chiral sulfur of the homogenous catalyst were perfectly remained in situ. And thus, the prepared catalysts demonstrated highly effective asymmetric cycloaddition activity, which was likely because the chiral induction effect of the Au complex was hardly influenced by this immobilization method. Moreover, they could be easily recovered by simple filtration and directly used for the subsequent catalytic runs. The prepared catalyst was highly stable and efficient without obvious activity loss after eight cycles.