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Sub‐5 nm Intermetallic Nanoparticles Confined in Mesoporous Silica Wells for Selective Hydrogenation of Acetylene to Ethylene
Author(s) -
MaligalGanesh Raghu V.,
Pei Yuchen,
Xiao Chaoxian,
Chen Minda,
Goh Tian Wei,
Sun Weijun,
Wu Jiashu,
Huang Wenyu
Publication year - 2020
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.202000155
Subject(s) - intermetallic , acetylene , bimetallic strip , materials science , nanoparticle , mesoporous silica , catalysis , ethylene , mesoporous material , chemical engineering , selectivity , dispersity , inorganic chemistry , chemistry , nanotechnology , alloy , organic chemistry , metallurgy , polymer chemistry , engineering
We report the synthesis and catalytic application of intermetallic PtSn nanoparticles confined in MSWs (Mesoporous Silica Wells) in the semi‐hydrogenation of acetylene. Platinum nanoparticles with a size of 2.9 nm supported on amine‐functionalized ∼180 nm silica spheres were enmeshed in a mesoporous silica shell. After the addition of tin via a polyol synthesis method, we obtained the final PtSn x @MSW (x=0.30, 0.50, 0.70, 1.0 and 2.0). Owing to the mesoporous encapsulation the sub‐5 nm bimetallic particles are shown to be monodisperse and well protected against aggregation on the silica sphere even under high‐temperature treatment conditions. In the gas phase semi‐hydrogenation of acetylene, the PtSn@MSW with Sn/Pt molar ratios equal to or greater than one displayed higher selectivity to ethylene. Meanwhile, increasing Sn content decreases acetylene conversion. The intermetallic PtSn@MSW catalysts also displayed long‐term stability and regenerability due to the confined environment provided by MSW.