High Catalytic Activity of Crystalline Lithium Calcium Silicate for Oxidative Coupling of Methane Originated from Crystallographic Joint Effects of Multiple Cations

The oxidative coupling of methane (OCM) to C 2 hydrocarbons is one of the most attractive catalytic processes towards the effective utilization of methane. Despite a great deal of effort in past research, the primary activation factor for OCM has still been unclear because of the chemical and structural complexities of known catalysts such as Mn−Na 2 WO 4 /SiO 2 . Here, we report a high catalytic activity of a crystalline oxide Li 2 CaSiO 4 for OCM. The C 2 selectivity and CH 4 conversion reach 77.5 % and 28.3 %, respectively, at 750 °C, which are comparable to or even higher than those with Mn−Na 2 WO 4 /SiO 2 . The simplicity of active sites in our single‐phase Li 2 CaSiO 4 catalyst facilitates a deeper understanding of the reaction mechanism, which leads to a crystallographic design concept for highly active OCM catalysts containing multiple cations.