Premium
Natural Deep Eutectic Solvents as Performance Additives for Peroxygenase Catalysis
Author(s) -
Ma Yunjian,
Li Yongru,
Ali Shahid,
Li Peilin,
Zhang Wuyuan,
Rauch Marine C. R.,
Willot Sébastien J.P.,
Ribitsch Doris,
Choi Young Hae,
Alcalde Miguel,
Hollmann Frank,
Wang Yonghua
Publication year - 2020
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201901842
Subject(s) - choline chloride , stabiliser , deep eutectic solvent , chemistry , eutectic system , green chemistry , catalysis , biocatalysis , reagent , solvent , organic chemistry , combinatorial chemistry , ionic liquid , food science , alloy
Natural deep eutectic solvents (NADES) are proposed as alternative solvents for peroxygenase‐catalysed oxyfunctionalization reactions. Choline chloride‐based NADES are of particular interest as they can serve as solvent, enzyme‐stabiliser and sacrificial electron donor for the in situ H 2 O 2 generation. This report provides the first proof‐of‐concept and basic characterisation of this new reaction system. Highly promising turnover numbers for the biocatalysts of up to 200,000 have been achieved.