Reductive Cycloisomerization of Diynes by Supported Palladium Catalysts and Subsequent [4+2] Cycloaddition for One‐Pot Synthesis of Cyclohexenes | Zendy

Miura Hiroki | Zendy; Tanaka Yumi | Zendy; Nakahara Karin | Zendy; Shishido Tetsuya | Zendy

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Reductive Cycloisomerization of Diynes by Supported Palladium Catalysts and Subsequent [4+2] Cycloaddition for One‐Pot Synthesis of Cyclohexenes

Author(s) -

Miura Hiroki,

Tanaka Yumi,

Nakahara Karin,

Shishido Tetsuya

Publication year - 2020

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201901423

Subject(s) - cycloisomerization , cycloaddition , catalysis , chemistry , palladium , cyclohexene , intermolecular force , organic chemistry , photochemistry , combinatorial chemistry , medicinal chemistry , molecule

Abstract : Supported Pd nanoparticles catalyzed the reductive cycloisomerization of diynes to give 1,3‐dienes, and subsequent intermolecular [4+2] cycloaddition with dienophiles led to cyclohexene derivatives. Various diynes and dienophiles participated in the one‐pot reaction to give the corresponding products in good to high yields. Al 2 O 3 ‐supported Pd catalysts were highly tolerant toward air and reusable.

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