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Binary Pd−Ni Nanoalloy Particles over Carbon Support with Superior Alkaline Formate Fuel Electrooxidation Performance
Author(s) -
Sankar Sasidharan,
Anilkumar Gopinathan M.,
Tamaki Takanori,
Yamaguchi Takeo
Publication year - 2019
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201900960
Subject(s) - overpotential , formate , catalysis , electrochemistry , alkaline fuel cell , chemistry , chemical engineering , materials science , carbon fibers , direct ethanol fuel cell , inorganic chemistry , organic chemistry , electrolyte , proton exchange membrane fuel cell , composite number , electrode , composite material , engineering
Formate is the one legitimate carbon‐neutral fuel that has the capability of being considered an alternative to alcohol fuels amidst the growing demand for efficient fuel‐cell systems. In this manuscript, we demonstrate, for the first time, a class of binary Pd−Ni alloy nanoparticles over two different carbon supports showing exceptional enhancement of the formate oxidation reaction (FOR) performance in alkaline medium, compared to Pd/C. The synergistic effects of Pd and oxophilic Ni along with the electronic structure alteration of Pd induced through alloying resulted in an effective change in its catalytic ability, leading to a 5‐time enhancement in the overall current density along with a lower overpotential during formate oxidation compared to Pd/C. The more active Pd catalytic sites of the nanoalloy helped to yield mass activities as high as 4.5 A mg −1 Pd and 7.8 A mg −1 Pd during FOR. The structural and electrochemical analysis justifies the synergistic effects and alterations in the Pd lattice ensuing a superior enhancement of electrochemically active Pd sites.