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Photocatalytic Transformation of Amines to Imines by Meso‐Porous Copper Sulfides
Author(s) -
Dutta Biswanath,
Achola Laura A.,
Clarke Ryan,
Sharma Vinit,
He Junkai,
Kerns Peter,
Suib Steven L.
Publication year - 2019
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201900673
Subject(s) - copper , imine , photocatalysis , chemistry , catalysis , mesoporous material , sulfide , copper sulfide , amine gas treating , hydrothermal circulation , porosity , heterogeneous catalysis , kinetics , photochemistry , inorganic chemistry , chemical engineering , organic chemistry , physics , quantum mechanics , engineering
Here we have demonstrated a visible‐light‐driven catalytic process for amine to imine transformations, using a hydrothermal procedure based mesoporous copper sulfide material. The surface chemistry of this heterogeneously catalyzed process, which was further supported by computational calculations, was determined by the reaction kinetics, and reactive oxygen determination studies.