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A Reusable Cobalt Catalyst for Reversible Acceptorless Dehydrogenation and Hydrogenation of N‐Heterocycles
Author(s) -
Jaiswal Garima,
Subaramanian Murugan,
Sahoo Manoj K.,
Balaraman Ekambaram
Publication year - 2019
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201900367
Subject(s) - dehydrogenation , catalysis , cobalt , chemistry , context (archaeology) , hydrogen storage , raw material , hydrogen , combinatorial chemistry , organic chemistry , paleontology , biology
The development of robust catalytic systems based on base‐metals for reversible acceptorless dehydrogenation (ADH) and hydrogenation of feedstock chemicals is very important in the context of ‘hydrogen storage’. Herein, we report a highly efficient reusable cobalt‐based heterogeneous catalyst for reversible dehydrogenation and hydrogenation of N‐heterocycles. Both the ADH and the hydrogenation processes operate under mild, benign conditions.