Manganese‐Catalyzed Transfer Hydrogenation of Aldimines | Zendy

Wei Duo | Zendy; BruneauVoisine Antoine | Zendy; Dubois Maxime | Zendy; Bastin Stéphanie | Zendy; Sortais JeanBaptiste | Zendy

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Manganese‐Catalyzed Transfer Hydrogenation of Aldimines

Author(s) -

Wei Duo,

BruneauVoisine Antoine,

Dubois Maxime,

Bastin Stéphanie,

Sortais JeanBaptiste

Publication year - 2019

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201900314

Subject(s) - aldimine , manganese , yield (engineering) , catalysis , transfer hydrogenation , chemistry , phosphine , medicinal chemistry , organic chemistry , polymer chemistry , materials science , metallurgy , ruthenium

The reduction of imines to amines via transfer hydrogenation was achieved promoted by phosphine‐free manganese(I) catalyst. Using isopropanol as reductant, in the presence of t BuOK (4 mol %) and manganese complex [Mn(CO) 3 Br(κ 2 N,N‐PyCH 2 NH 2 )] (2 mol %), a large variety of aldimines (30 examples) were typically reduced in 3 hours at 80 °C with good to excellent yield.

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