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Cover Feature: Homogeneous Catalytic Reduction of CO 2 with Silicon‐Hydrides, State of the Art (ChemCatChem 1/2019)
Author(s) -
FernándezAlvarez Francisco J.,
Oro Luis A.
Publication year - 2019
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201801977
Subject(s) - catalysis , silylation , chemistry , silicon , cover (algebra) , oxidation state , homogeneous , combinatorial chemistry , photochemistry , organic chemistry , physics , engineering , mechanical engineering , thermodynamics
The Cover Feature shows the formation of silylformates, bis(silyl)acetals or methoxysilanes by catalytic reduction of CO 2 with hydrosilanes. In their Full Paper, F. J. Fernández‐Alvarez and L. A. Oro summarize the different catalytic systems that have shown to be efficient for the transformation of CO 2 into value added chemicals using silicon‐hydrides as reductants. Moreover, a description of some catalysts that have been employed for the formylation and/or methylation of the N−H bonds of secondary and/or primary amines by their reaction with CO 2 and hydrosilanes have also been included. In addition, this Review also contains a brief description of the performance and conditions of each reaction. More information can be found in the Full Paper by F. J. Fernández‐Alvarez and L. A. Oro on page 4783 in Issue 21, 2018 (DOI: 10.1002/cctc.201800699).