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Facile Synthesis of a High Performance NiPd@CMK‐3 Nanocatalyst for Mild Suzuki‐Miyaura Coupling Reactions
Author(s) -
Park Ji Chan,
Kim Aram,
Jang Sanha,
Yang JungIl,
Kang Shin Wook,
Lee ChanWoo,
Kim ByungHyun,
Park Kang Hyun
Publication year - 2019
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201801872
Subject(s) - phenylboronic acid , bimetallic strip , catalysis , palladium , nanoparticle , coupling reaction , nickel , suzuki reaction , mesoporous material , metal , materials science , chemistry , nuclear chemistry , combinatorial chemistry , chemical engineering , nanotechnology , organic chemistry , engineering
Highly dispersed nickel‐palladium bimetallic nanoparticles (∼2 nm) on ordered mesoporous carbon CMK‐3 (NiPd@CMK‐3) were simply prepared using a co‐infiltration method of the metal salts. The nanoparticles were successfully applied to the mild Suzuki‐Miyaura coupling reactions at 25∼50 °C using 4‐bromoanisole and phenylboronic acid, and showed excellent catalytic performance with the high activity (0.521×10 −3 mol c ⋅ g am −1 ⋅ s −1 ) and productivity (69.1 g p ⋅ g cat −1 ⋅ h −1 ).
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