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Manganese‐Catalyzed C−H Olefination Reactions
Author(s) -
Hu Yuanyuan,
Wang Congyang
Publication year - 2019
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201801787
Subject(s) - manganese , catalysis , chemistry , olefin fiber , transition metal , organic chemistry , organic synthesis , combinatorial chemistry
Olefins are essential building blocks in organic synthesis, the access to which from simple C−H substrates through catalysis of transition metals, in particular the earth's abundant ones meets the requirements of green and sustainable chemistry. Manganese‐catalyzed C−H olefination reactions have emerged as an efficient approach to olefins in recent years, complementary to traditional olefin synthesis. Varieties of alkynes, alkenes, allenes as well as alcohols are successfully applied to the Mn‐catalyzed reactions with C−H substrates, providing multisubstituted olefins bearing varied functional groups. This minireview presents great progresses newly achieved on manganese‐catalyzed C−H olefination reactions.