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Oxygen Vacancy‐rich Anatase TiO 2 Hollow Spheres Via Liquid Nitrogen Quenching Process for Enhanced Photocatalytic Hydrogen Evolution
Author(s) -
Wang Gan,
Zhang Lijuan,
Yan Baolin,
Luo Jianmin,
Su Xintai,
Yue Fan
Publication year - 2019
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201801721
Subject(s) - anatase , photocatalysis , quenching (fluorescence) , materials science , chemical engineering , oxygen , hydrogen , nitrogen , water splitting , x ray photoelectron spectroscopy , catalysis , chemistry , organic chemistry , optics , physics , fluorescence , engineering
Abstract Development of novel methods to obtain highly active catalysts for photocatalytic hydrogen evolution is desired. This work reports a facile preannealing‐quenching strategy to synthesize oxygen vacancy‐rich anatase TiO 2 hollow spheres. TiO 2 hollow spheres are first synthesized via a versatile kinetics‐controlled coating method and then subjected to high temperature preannealing followed by rapid quenching in liquid‐nitrogen (−196 °C). The as‐quenched samples appear light grey suggesting the presence of abundant surface oxygen vacancies, which are subsequently confirmed by the comprehensive analyses of XRD, XPS and EPR spectra. The oxygen vacancies induced by quenching process are proved to have promoted the light adsorption and inhibited the recombination of photo‐induced charges for TiO 2 hollow spheres, which obviously improve the photocatalytic performance of those samples. The results showed that the TiO 2 hollow spheres quenched at 500 °C exhibited a robust stability and the most excellent photocatalytic performance for hydrogen evolution (413.5 μmol h −1 ) over other quenched samples and it displayed 1.51 times higher performance than that of samples normally cooled at 500 °C (273.7 μmol h −1 ). Herein, this liquid‐nitrogen quenching strategy presented here provides an effective route for the synthesis of high‐performance TiO 2 for water splitting and have a promising prospect in the other application.